Specific Heat
Specific heat is the heat needed to raise the temperature of unit mass of a substance by one degree: . It tells you how "thermally stubborn" a material is: water, with the largest specific heat of common substances, warms and cools slowly. This page builds the language of heat (calorie, joule, mechanical equivalent, temperature scales) and then specific heat, heat capacity, molar specific heat and water equivalent, which are asked directly in NEET and JEE Main and are used in every calorimetry problem.
- ★ Must learn (constant ); when varies
- ★ Must learn; a change of
- Mechanical equivalent of heat: , (1 cal )
- ★ Must learnSpecific heat of water ; ice and steam
- Heat capacity (thermal capacity) , unit
- Molar specific heat , unit ; gases:
- ★ Must learnWater equivalent ( in calorie units), unit kg or g
- Solids (Dulong-Petit): at room temperature
1. Heat, Temperature and Internal Energy
Heat is the energy transferred between two bodies (or two parts of a body) because of a temperature difference. It is energy in transit: once it arrives it becomes part of the internal energy of the receiving body. So "heat in a body" is meaningless; a body has internal energy.
Temperature is the property that decides the direction of heat flow: heat flows from higher to lower temperature, never the reverse on its own. When two bodies in contact stop exchanging heat they are in thermal equilibrium and have the same temperature. The zeroth law of thermodynamics (two bodies each in equilibrium with a third are in equilibrium with each other) is what lets a thermometer measure temperature.
| Heat | Temperature |
|---|---|
| Energy in transit due to a temperature difference | Degree of hotness; decides the direction of heat flow |
| SI unit joule (J); also calorie (cal) | SI unit kelvin (K); also °C, °F |
| Depends on mass, material and temperature change | Does not depend on the amount of matter |
| Microscopic view: transfer of random kinetic energy | Microscopic view: measure of average random kinetic energy of molecules |
When a body is heated, its molecules move (or vibrate) faster: their average kinetic energy, and so the temperature, rises.
2. Measuring Temperature: Scales
A thermometer uses a property that changes steadily with temperature (length of a mercury column, pressure of a gas at constant volume, resistance of a wire). Two fixed points are chosen: the ice point (melting of pure ice at 1 atm) and the steam point (boiling of pure water at 1 atm).
| Scale | Ice point | Steam point | Divisions between them |
|---|---|---|---|
| Celsius | 100 | ||
| Fahrenheit | 180 | ||
| Kelvin (absolute) | 100 |
For any temperature, the fraction of the way from ice point to steam point is the same on every scale:
General rule for any linear scale X with lower fixed point and upper fixed point : is the same on all scales.
Absolute temperature. A constant-volume gas thermometer shows pressure falling linearly with temperature; extended, every gas line reaches at the same temperature, . This absolute zero is the zero of the Kelvin scale: . For an ideal gas, with in kelvin. The triple point of water, (), is the modern fixed point of the Kelvin scale.
Differences convert without the offset. A temperature converts with or ; a temperature difference does not: and . That is why specific heat has the same number in and . For a faulty thermometer, use .
3. Mechanical Equivalent of Heat
Heat was once thought to be a fluid ("caloric") and was measured in calories. Joule showed that doing mechanical work on a system raises its temperature exactly as heat does, with a fixed exchange rate. If work produces the same effect as heat :
is not a physical constant but a conversion factor between two units of the same quantity (energy). In SI, heat is measured in joules directly and disappears.
1 calorie is the heat needed to raise the temperature of of water from to at 1 atm. and (the food "Calorie" is 1 kcal).
4. Specific Heat Capacity
Experiments show that the heat gained or lost by a body is proportional to its mass and to its change of temperature :
The specific heat capacity of a substance is the heat needed to raise the temperature of unit mass by one degree:
SI unit ; CGS unit ; dimensions . It depends on the material and its state (and slightly on temperature), not on the size of the body.
If depends on temperature, add up small steps: , so .
| Substance | () | Substance | () |
|---|---|---|---|
| Water | 4186 | Aluminium | 900 |
| Ice | 2060 | Glass | 840 |
| Kerosene | 2118 | Copper | 386.4 |
| Sea water | 3900 | Silver | 236.1 |
| Edible oil | 1965 | Lead | 127.7 |
Why water's high specific heat matters. Water absorbs a lot of heat for a small rise in temperature, so it is used as a coolant in car radiators and power plants, in hot-water bags, and it keeps coastal climates mild (the sea warms and cools slowly; this also drives sea and land breezes).
4.1 Specific heat of water varies slightly
The specific heat of water is not exactly constant. Between and it changes by less than 1%, with a shallow minimum near . For problems take ( or as the question says).
A body of mass has . What is its heat capacity?
Is the value of specific heat different in and ?
Why is the calorie defined between 14.5 °C and 15.5 °C?
5. Heat Capacity, Molar Specific Heat and Water Equivalent
5.1 Heat capacity (thermal capacity)
The heat capacity of a body is the heat needed to raise the temperature of the whole body by one degree:
Unit (CGS: ). It depends on both the material and the mass, so a bucket of water has a larger heat capacity than a cup of water, though both have the same specific heat.
Per unit mass. Property of the material. Unit . Same for a cup or a bucket of water.
For the whole body. Depends on mass too. Unit . A bucket of water has a larger than a cup.
5.2 Molar specific heat
Per mole instead of per kilogram: , where is the molar mass in . Unit .
- Solids: most metals have at room temperature (law of Dulong and Petit). Copper: . At low temperatures falls towards zero.
- Gases: the heat needed depends on the process. At constant volume ; at constant pressure . because at constant pressure part of the heat does work in expansion: (Mayer's relation) for an ideal gas.
| Gas type | |||
|---|---|---|---|
| Monatomic (He, Ar) | |||
| Diatomic (, ), room temperature | |||
| Non-linear polyatomic (), no vibration |
5.3 Water equivalent
The water equivalent of a body is the mass of water that would need the same heat as the body for the same rise in temperature:
In calorie units , so numerically (in grams). Its unit is that of mass. In calorimetry, a calorimeter of water equivalent is simply treated as extra grams of water.
6. Special Cases and the Right Formula
The ratio can be worked out for any process, and in some processes it gives strange values. These describe the process, not a new property of the material:
| Situation | |||
|---|---|---|---|
| Melting or boiling (phase change) | supplied | 0 | infinite: heat goes into latent heat |
| Adiabatic process (no heat exchanged, e.g. quick compression of a gas) | 0 | not zero | zero |
| Saturated water vapour kept saturated while heated (for information only) | must be removed | positive | negative |
| Ordinary heating at constant pressure | supplied | positive | the tabulated specific heat |
A liquid in a thermos flask that warms when shaken does not have zero specific heat. No heat enters, but work is done on it by the shaking: its internal energy and temperature rise through work, . Its specific heat is still the tabulated value.
For a gas the molar heat capacity depends on the path: isothermal process , adiabatic , isobaric , isochoric , and for a polytropic process : , which is negative when . When is given as a function of temperature, e.g. , always integrate: .
7. Solved Examples
.
Answer: . (Here .)
Energy lost to the surroundings is , so the block keeps : .
. The mass cancels.
Answer: .
(a) gives , and .
(b) Put : , so , giving .
Answer: (a) ; (b) , i.e. .
.
Answer: . (This faulty scale agrees with the true one only at .)
.
Answer: , independent of the mass.
.
Answer: .
.
.
Answer: .
.
Answer: . (Using the value of at the start, , would give only .)
Heat capacity .
Water equivalent .
Answer: (); .
(A)
(B)
(C)
(D)
Answer: (B). and : equal heat capacities give equal rises.
; .
Answer: , within 2% of (Dulong-Petit law).
- Convert and to Fahrenheit.Answer: ;
- How much heat raises of aluminium () from to ?Answer:
- A heater warms a block by in . Find the specific heat of the block (no losses).Answer:
- A body of heat capacity has mass . Find its specific heat and water equivalent.Answer: ; about
- What height must water fall so that its temperature rises by if all the energy stays in it? ()Answer: about
- Why is of a gas larger than ?Answer: At constant pressure part of the heat does work as the gas expands
- A thermometer reads at the ice point and at the steam point. What is the true temperature when it reads ?Answer: about
Common Mistakes to Avoid
- Adding to a temperature difference. in kelvin equals in .
- Using for water in SI problems. It is or ; keep units consistent (grams with calories, kilograms with joules).
- Confusing specific heat (per kg, material property) with heat capacity (whole body, depends on mass).
- Saying a body \"contains heat\". A body has internal energy; heat is only the energy transferred.
- Using across a melting or boiling point. Split the range and add at the phase change.
- Taking as a physical constant. It is only the number of joules in one calorie.
- Using the initial value of a temperature-dependent instead of integrating .
- In energy-conversion problems, forgetting to use only the fraction of energy that actually becomes heat in the body.
Frequently Asked Questions
What is specific heat capacity?
Specific heat capacity is the heat needed to raise the temperature of one kilogram of a substance by one kelvin. Its SI unit is . It is a property of the material: water has 4186, aluminium 900 and copper about 386.
What is the difference between specific heat and heat capacity?
Specific heat is per unit mass and belongs to the material. Heat capacity is for the whole body, , so it also depends on how much material there is. A bucket and a cup of water have the same specific heat but different heat capacities.
Why does water have a high specific heat and why does it matter?
Water molecules are held by hydrogen bonds, and much of the energy supplied goes into these bonds and molecular motions before the temperature rises. So water heats and cools slowly, which makes it an excellent coolant and keeps coastal climates mild.
What is the mechanical equivalent of heat?
It is the number of joules of work that produce the same heating as one calorie of heat: . Joule found it with a paddle wheel churning water. It is a conversion factor between units, not a physical constant.
What is water equivalent?
Water equivalent is the mass of water that needs the same heat as a given body for the same rise in temperature. It equals ; in calorie units it is simply , in grams.
Why is the specific heat of a gas at constant pressure greater than at constant volume?
At constant volume all the heat supplied raises the internal energy. At constant pressure the gas also expands and does work on its surroundings, so extra heat is needed for the same temperature rise. For an ideal gas .
How is specific heat asked in NEET?
NEET usually asks one direct question: heat needed for a temperature change, the ratio of temperature rises of two bodies, water equivalent, or conversion between temperature scales. Remember and that a Celsius degree equals a kelvin.
What type of specific heat questions come in JEE Main?
JEE Main mixes specific heat with energy conversion (falling bodies, bullets, heaters), temperature-dependent specific heat that must be integrated, faulty thermometer scales, and molar heat capacities of gases in different processes.
Previous year questions on Specific Heat
2 questions from past papers, each with a step-by-step solution.
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