PhysicsThermal Properties Of MatterFor JEE aspirants
Thermal expansion is the increase in the length, area or volume of a body when its temperature rises: ΔL=L0αΔT, ΔA=A0βΔT, ΔV=V0γΔT, with β=2α and γ=3α. This page explains why matter expands, covers solids, liquids (real and apparent expansion), gases and the anomalous expansion of water, and then the applications behind most thermal expansion questions in NEET and JEE Main: bimetallic strips, pendulum clocks, measuring scales and thermal stress.
On this page1Why bodies expand2Linear, area, volume3β = 2α, γ = 3α4Density and holes5Liquids6Water anomaly7Gases8Applications9Thermal stress
Key Formulas - Quick Reference
★ Must learnL=L0(1+αΔT), A=A0(1+βΔT), V=V0(1+γΔT)
★ Must learnIsotropic solid: α:β:γ=1:2:3; anisotropic: γ=αx+αy+αz
Density: ρ=1+γΔTρ0≈ρ0(1−γΔT)
★ Must learnLiquids: γreal=γapparent+γvessel; overflow =V0(γliquid−γvessel)ΔT
Ideal gas at constant pressure: γ=T1 (3.66×10−3K−1 at 0∘C)
★ Must learnThermal stress (expansion prevented): σ=YαΔT, force F=YAαΔT
Pendulum clock: TpΔTp=21αΔθ; time lost per day =21αΔθ×86400s
1. What Is Thermal Expansion and Why Does It Happen?
Most substances expand when heated and contract when cooled. A railway track, a bridge, a mercury column and a hot-air balloon all show it. The increase in dimensions of a body due to a rise in temperature is called thermal expansion.
Microscopic reason. Atoms in a solid vibrate about their mean positions in a potential energy well. The well is not symmetric: it rises steeply when atoms are pushed together (strong repulsion) and gently when they are pulled apart. At higher temperature the atoms vibrate with more energy between two turning points, and the midpoint of these points moves to a larger separation. So the average spacing, and the size of the body, grows.
Figure 1: The interatomic potential energy curve is not symmetric (drawn from a Morse potential). As temperature rises, atoms vibrate with more energy and the mid-point of their vibration (red dots) moves to larger separation: the solid expands. A symmetric (parabolic) well would give no expansion.
Key idea
Expansion comes from the asymmetry of the interatomic potential: more vibration energy means a larger average spacing.
2. Linear, Area and Volume Expansion
★ Must learn
For a small temperature change ΔT, the fractional change in size is proportional to ΔT:
L0ΔL=αΔT,A0ΔA=βΔT,V0ΔV=γΔT
α = coefficient of linear expansion, β = coefficient of area (superficial) expansion, γ = coefficient of volume (cubical) expansion. Unit K−1 (same number per ∘C). They are characteristic of the material and vary slightly with temperature.
Figure 2: The three kinds of thermal expansion (exaggerated). Dashed outlines are before heating. α, β and γ are the fractional changes in length, area and volume per kelvin.
Material
α (10−5K−1)
Material
α (10−5K−1)
Aluminium
2.5
Gold
1.4
Brass
1.8
Iron
1.2
Copper
1.7
Glass (pyrex)
0.32
Silver
1.9
Invar
0.09
Metals have α∼10−5K−1: a 1m steel rod lengthens by only about 0.1mm per 10K. Invar (an iron-nickel alloy) barely expands, so it is used for pendulums, measuring tapes and precision instruments. Pyrex glass expands little, so it survives sudden heating.
2.1 Relation between α, β and γ
A square of side L heated by ΔT has side L(1+αΔT) and area L2(1+αΔT)2=L2(1+2αΔT+α2ΔT2).
αΔT∼10−3, so the squared term is negligible: ΔA=L2(2α)ΔT, i.e. β=2α.
A cube: V=L3(1+αΔT)3≈L3(1+3αΔT), so γ=3α.
Figure 3: The extra area is two strips LΔL plus a corner (ΔL)2 that is negligible because ΔL≪L. Hence β=2α and, for volume, γ=3α.
★ Must learn
For an isotropic solid: β=2α, γ=3α, i.e. α:β:γ=1:2:3. For an anisotropic crystal with different expansivities along three axes: βxy=αx+αy and γ=αx+αy+αz.
3. Consequences: Holes, Cavities and Density
A hole expands like the material around it. A hole in a plate, the bore of a ring or the cavity of a hollow sphere grows on heating exactly as if it were filled with the same material. So a ring can be heated to slip over a slightly larger rod (shrink fitting), and a tight metal lid on a glass jar loosens in hot water.
Density falls on heating because the mass is unchanged while the volume grows: ρ=1+γΔTρ0≈ρ0(1−γΔT).
Hollow and solid spheres of the same material and outer radius expand equally in outer size.
Figure 4: Heating is a uniform photographic enlargement (exaggerated here): every length, including the diameter of a hole, grows by the same factor (1+αΔT). This is how a tight metal lid is loosened with hot water.
4. Expansion of Liquids: Real and Apparent
A liquid has no fixed shape, so only its volume expansion is defined. Liquids expand more than solids (γ∼10−4 to 10−3K−1). A liquid is always heated in a vessel that also expands, so what we observe is not the full story.
Figure 5: A heated liquid first seems to shrink (the vessel warms and expands first), then rises. What we see is the apparent expansion: γreal=γapparent+γvessel.
★ Must learn
γreal=γapparent+γvessel
Real expansion is the actual increase in volume of the liquid; apparent expansion is the increase seen against the vessel's markings. If the vessel is full, the volume that overflows is V0(γliquid−γvessel)ΔT. If γvessel=γliquid nothing overflows; if γvessel is larger, the level falls.
Substance
γ (10−5K−1)
Substance
γ (10−5K−1)
Alcohol (ethyl)
110
Glass (ordinary)
2.5
Paraffin
58.8
Glass (pyrex)
1.0
Water
20.7
Iron
3.55
Mercury
18.2
Aluminium
7.0
Exam Trick
Constant empty volume inside a vessel. If a glass vessel of volume V holds mercury of volume Vm and the space above the mercury must stay the same at every temperature, the two expansions must be equal: Vγglass=VmγHg, so Vm=γHgVγglass. The same idea fixes a constant difference in length between two rods: L1α1=L2α2.
5. Anomalous Expansion of Water
Water behaves unusually between 0∘C and 4∘C: on heating, it contracts. Its density is maximum (about 1000kg m−3) at about 4∘C; above 4∘C it expands like other liquids. On freezing, water expands by about 9%, which is why ice floats and why water pipes burst in winter.
Figure 6: Water is densest at about 4∘C (curve from the Kell equation). Between 0 and 4∘C it contracts on heating (γ<0); above 4∘C it expands normally. Volume of a fixed mass is least at 4∘C.
Why lakes freeze from the top. As a lake cools, the cooler surface water is denser and sinks until the whole lake reaches 4∘C. Below 4∘C the surface water becomes lighter and stays on top, cools to 0∘C and freezes. Ice is a poor conductor, so the water underneath stays at about 4∘C and aquatic life survives.
Figure 7: Water at 4∘C is densest and sinks; colder water and ice float. Ice, a poor conductor, insulates the water below, so lakes freeze from the top down and aquatic life survives.
Quick Recall: tap to checkAt what temperature is the volume of a given mass of water least?
About 4∘C.
What is γ for water between 0 and 4∘C?
Negative: water contracts on heating in this range.
Why does a glass bottle full of water crack in a freezer?
Water expands by about 9% on freezing.
6. Expansion of Gases
Gases expand far more than solids and liquids, and their expansion depends strongly on pressure, so it is quoted at constant pressure. For an ideal gas pV=μRT; at constant p, V∝T (Charles's law), so
γ=V1(∂T∂V)p=T1
At 0∘C this is 273.151=3.66×10−3K−1, hundreds of times larger than for solids, and it decreases as temperature rises.
Figure 8: At constant pressure V∝T (Charles's law), so γ=V1dTdV=T1: about 3.66×10−3K−1 at 0∘C, much larger than for solids or liquids, and it depends on temperature.
7. Applications of Thermal Expansion
7.1 Bimetallic strip
Two metals with different α (say brass and iron) are riveted or welded along their length. On heating, brass expands more, so the strip bends with brass on the convex side. On cooling it bends the other way. For strips of thickness d each, the radius of curvature is R=(α1−α2)ΔTd. Used in thermostats (electric irons, ovens), fire alarms, car indicator flashers and dial thermometers.
Figure 9: A bimetallic strip bends because the two metals expand by different amounts (curvature exaggerated). The metal with the larger α is on the outside of the curve. Used in thermostats, fire alarms and flashers.
7.2 Pendulum clocks
Period Tp=2πgL, so TpΔTp=21LΔL=21αΔθ.
A longer period means fewer oscillations per day: in summer the clock loses time; in winter it gains.
Time lost or gained in a time t: Δt=21αΔθ×t; per day, t=86400s.
Figure 10: A metal pendulum lengthens on heating, so its period grows by the fraction 21αΔθ and the clock loses time (drawn exaggerated). Invar pendulums (α tiny) keep good time.
7.3 Measuring scales
A metal scale is correct at the temperature at which it was calibrated. At a higher temperature each division is longer, so the scale reads less than the true length: true length = reading ×(1+αsΔθ), where αs is for the scale and Δθ is measured from the calibration temperature. If the object also expands, use the difference of expansivities.
7.4 Everyday examples
Gaps are left between rails and in bridges (expansion joints); telephone and power lines sag more in summer.
Thick glass tumblers crack when hot water is poured in: the inside expands before the outside. Pyrex, with small α, does not.
Platinum is sealed into glass because their α values are nearly equal.
Rivets are put in red-hot: on cooling they contract and grip the plates tightly. Iron tyres are heated before fitting on wooden wheels.
8. Thermal Stress
If a rod is fixed between rigid walls and heated, it cannot expand. The walls compress it by exactly the length it wanted to gain, LαΔT, so its strain is αΔT and
thermal stress=YαΔT,F=YAαΔT
The stress does not depend on the length of the rod. On cooling a clamped rod, the stress is tensile. Thermal stress is why rails buckle in heat waves if expansion gaps are too small.
Figure 11: If expansion is prevented, the body is strained by αΔT and a thermal stress YαΔT appears, whatever its length. Gaps in rails and bridges, and loops in pipelines, avoid this.
JEE Advanced
Temperature-dependent α:LdL=α(T)dT gives L=L0exp(∫T0TαdT)≈L0(1+∫T0TαdT). Two rods in series between walls (lengths L1, L2, same area): total free expansion L1α1ΔT+L2α2ΔT must be cancelled, and the same force acts in both: F(AY1L1+AY2L2)=(L1α1+L2α2)ΔT. Moment of inertia of a heated body: I∝L2, so IΔI=2αΔT, and a freely spinning disc slows down (Iω constant): ωΔω=−2αΔT.
Figure 12: Four problem types cover almost every thermal expansion question. Identify which one before choosing a formula.Figure 13: Mind map of thermal expansion for quick revision.
9. Solved Examples
Solved Example 1
An aluminium rod is 1.0m long at 20∘C. Find its length at 70∘C. (α=2.5×10−5K−1)
Solution:
ΔL=L0αΔT=(1.0)(2.5×10−5)(50)=1.25×10−3m.
Answer: L=1.00125m (it grows by 1.25mm).
Solved Example 2
A blacksmith fixes an iron ring on the rim of a wooden wheel. At 27∘C the diameters of the rim and the ring are 5.243m and 5.231m. To what temperature must the ring be heated to fit the rim? (αiron=1.20×10−5K−1)
Solution:
The ring's diameter must grow by 0.012m: 0.012=5.231×1.20×10−5×ΔT, so ΔT=191K.
Answer: T≈27+191=218∘C.
Solved Example 3
A hole is drilled in a copper sheet. Its diameter is 4.24cm at 27∘C. What is its diameter at 227∘C? (αCu=1.70×10−5K−1)
Solution:
The hole expands like copper: Δd=dαΔT=4.24×1.70×10−5×200=1.44×10−2cm.
Answer: d≈4.2544cm (it increases).
Solved Example 4
A brass wire 1.8m long at 27∘C is held taut with little tension between two rigid supports. If it is cooled to −39∘C, what is the tension? (Diameter 2.0mm, α=2.0×10−5K−1, Y=0.91×1011Pa)
Solution:
The wire wants to shorten by LαΔT but cannot: strain =αΔT, so F=YAαΔT.
F=(0.91×1011)π(1.0×10−3)2(2.0×10−5)(66).
Answer: F≈3.8×102N (tension; independent of length).
Solved Example 5
A steel rod is clamped between two rigid walls at room temperature and heated by 50∘C. Find the thermal stress. (Y=2×1011Pa, α=1.2×10−5K−1)
Solution:
Stress =YαΔT=(2×1011)(1.2×10−5)(50).
Answer: 1.2×108Pa, compressive.
Solved Example 6
A pendulum clock with a steel pendulum (α=1.2×10−5K−1) keeps correct time at 20∘C. How many seconds does it lose or gain per day at 40∘C?
Solution:
TpΔTp=21αΔθ=21(1.2×10−5)(20)=1.2×10−4.
Per day: 1.2×10−4×86400.
Answer: it loses about 10.4s per day (period longer, clock slow).
Solved Example 7
A glass flask of volume 1000cm3 is completely filled with mercury at 0∘C. How much mercury overflows when both are heated to 100∘C? (γHg=18.2×10−5K−1, γglass=2.5×10−5K−1)
The density of mercury is 13.6g cm−3 at 0∘C. Find its density at 100∘C. (γ=18.2×10−5K−1)
Solution:
ρ=1+γΔTρ0=1+0.018213.6.
Answer: ρ≈13.36g cm−3.
Solved Example 9
A steel scale is correct at 20∘C. A length measured with it at 40∘C reads 50.00cm. What is the true length? (αsteel=1.2×10−5K−1)
Solution:
At 40∘C each division is longer by the factor (1+αΔθ), so the scale reads low: true =50.00(1+1.2×10−5×20).
Answer: 50.012cm.
Solved Example 10
A bimetallic strip is made of brass (α=1.8×10−5K−1) and iron (α=1.2×10−5K−1) strips, each 0.5mm thick. Find its radius of curvature when heated by 100K.
Solution:
R=(α1−α2)ΔTd=(0.6×10−5)(100)0.5×10−3.
Answer: R≈0.83m, with brass on the outer side.
Solved Example 11
The coefficient of linear expansion of a solid is 1.0×10−5K−1. Its coefficient of volume expansion is (A) 1.0×10−5 (B) 2.0×10−5 (C) 3.0×10−5 (D) 3.3×10−6K−1
Solution:
Answer: (C). For an isotropic solid γ=3α.
Solved Example 12
Water at 0∘C is heated to 10∘C. Its volume (A) increases steadily (B) decreases steadily (C) first decreases, then increases (D) first increases, then decreases
Solution:
Answer: (C). Water contracts from 0 to 4∘C (volume least at 4∘C) and then expands.
Solved Example 13
Find the coefficient of volume expansion of an ideal gas at constant pressure at 27∘C.
Solution:
γ=T1=300K1.
Answer: γ≈3.3×10−3K−1.
Practice Questions
A 10m steel rail (α=1.2×10−5K−1) is laid at 15∘C. What gap is needed for 45∘C?Answer: 3.6mm
A metal plate's area grows by 0.2% when heated by 50K. Find α.Answer: 2×10−5K−1
By what percentage does the density of a solid (α=2×10−5K−1) fall when heated by 100K?Answer: about 0.6%
An iron rod and a copper rod must differ in length by 10cm at all temperatures. Find their lengths. (αFe=1.2, αCu=1.7, both ×10−5K−1)Answer: iron 34cm, copper 24cm
A clock with a brass pendulum (α=1.9×10−5K−1) is correct at 25∘C. Does it gain or lose at 5∘C, and by how much per day?Answer: gains about 16.4s
Why does a thick glass tumbler crack when boiling water is poured into it?Answer: The inner surface expands before the outer; the uneven expansion sets up stresses
A liquid has γ=5×10−4K−1 and is in a vessel with γ=5×10−5K−1. Find its apparent expansivity.Answer: 4.5×10−4K−1
Common Mistakes to Avoid
Watch out
Thinking a hole in a plate shrinks on heating. It expands, like the material around it.
Using γ=3α for a liquid. Liquids have only γ; α is not defined for them.
Forgetting the vessel: the observed (apparent) expansion is γreal−γvessel.
Saying a pendulum clock gains time in summer. The pendulum lengthens, so the clock loses time.
Writing thermal stress as YαLΔT: the stress YαΔT is independent of length.
Assuming water always expands on heating; between 0 and 4∘C it contracts.
Putting the metal with the larger α on the concave side of a heated bimetallic strip; it is on the convex side.
Taking γ of a gas as a constant; at constant pressure it is T1 and falls as T rises.
Frequently Asked Questions
What is thermal expansion?
Thermal expansion is the increase in length, area or volume of a body when its temperature rises. For a small temperature change the fractional change is proportional to the temperature change, with coefficients α (length), β (area) and γ (volume).
What is the relation between alpha, beta and gamma?
For an isotropic solid the area coefficient is twice and the volume coefficient three times the linear coefficient, so α:β:γ=1:2:3. It follows from squaring or cubing (1+αΔT) and dropping small terms.
Why do solids expand on heating?
The potential energy curve between two atoms is steeper on the compression side than on the stretching side. When atoms vibrate with more energy at higher temperature, the midpoint of their vibration shifts to a larger separation, so the average spacing increases.
What is the anomalous expansion of water?
Between 0 and 4∘C water contracts when heated instead of expanding, so its density is maximum at about 4∘C. Because of this, lakes freeze from the top and the water at the bottom stays near 4∘C, allowing fish to survive.
What is the difference between real and apparent expansion of a liquid?
Real expansion is the actual increase in volume of the liquid. Apparent expansion is what is observed against the markings of the vessel, which also expands. γreal=γapp+γvessel.
Why does a pendulum clock lose time in summer?
Heat lengthens the metal pendulum, and the time period is proportional to the square root of the length. A longer period means fewer ticks per day, so the clock runs slow. The fractional change in period is 21αΔθ for a temperature rise Δθ.
How is thermal expansion asked in NEET?
NEET asks about the ratio α:β:γ, expansion of holes, the anomalous expansion of water, bimetallic strips and simple numericals on the change in length, area, volume or density. Thermal stress also appears with Young's modulus.
Which thermal expansion problems are common in JEE Main?
JEE Main uses pendulum clocks losing or gaining time, apparent expansion and overflow of liquids, thermal stress and force in clamped rods, rods with a constant length difference, scale corrections and the change in moment of inertia or angular speed on heating.
Previous year questions on Thermal Expansion
5 questions from past papers, each with a step-by-step solution.