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Thermal Expansion

PhysicsThermal Properties Of MatterFor NEET aspirants

Thermal expansion is the increase in the length, area or volume of a body when its temperature rises: , , , with and . This page explains why matter expands, covers solids, liquids (real and apparent expansion), gases and the anomalous expansion of water, and then the applications behind most thermal expansion questions in NEET and JEE Main: bimetallic strips, pendulum clocks, measuring scales and thermal stress.

On this page1Why bodies expand2Linear, area, volume3β = 2α, γ = 3α4Density and holes5Liquids6Water anomaly7Gases8Applications9Thermal stress
Key Formulas - Quick Reference
  1. ★ Must learn, ,
  2. ★ Must learnIsotropic solid: ; anisotropic:
  3. Density:
  4. ★ Must learnLiquids: ; overflow
  5. Ideal gas at constant pressure: ( at )
  6. ★ Must learnThermal stress (expansion prevented): , force
  7. Pendulum clock: ; time lost per day
  8. Bimetallic strip: radius ; scale reading: true value reading

1. What Is Thermal Expansion and Why Does It Happen?

Most substances expand when heated and contract when cooled. A railway track, a bridge, a mercury column and a hot-air balloon all show it. The increase in dimensions of a body due to a rise in temperature is called thermal expansion.

Microscopic reason. Atoms in a solid vibrate about their mean positions in a potential energy well. The well is not symmetric: it rises steeply when atoms are pushed together (strong repulsion) and gently when they are pulled apart. At higher temperature the atoms vibrate with more energy between two turning points, and the midpoint of these points moves to a larger separation. So the average spacing, and the size of the body, grows.

Why solids expand: the asymmetric potential energy curve between two atoms Potential energy of a pair of atoms against their separation r. The curve is steep on the compression side and gentle on the stretching side, with a minimum at r0. Horizontal lines show the vibration energy at three increasing temperatures; the midpoint of each line, the mean separation, moves to larger r as temperature rises. r U(r) r0 T1 T2 > T1 T3 > T2 mean separation (red dots) shifts right steep repulsive side gentle attractive side
Figure 1: The interatomic potential energy curve is not symmetric (drawn from a Morse potential). As temperature rises, atoms vibrate with more energy and the mid-point of their vibration (red dots) moves to larger separation: the solid expands. A symmetric (parabolic) well would give no expansion.
Key idea
Expansion comes from the asymmetry of the interatomic potential: more vibration energy means a larger average spacing.

2. Linear, Area and Volume Expansion

★ Must learn

For a small temperature change , the fractional change in size is proportional to :

= coefficient of linear expansion, = coefficient of area (superficial) expansion, = coefficient of volume (cubical) expansion. Unit (same number per ). They are characteristic of the material and vary slightly with temperature.

Linear, area and volume expansion of a solid on heating Three panels. Left: a rod of length L0 becomes longer by delta L when heated by delta T. Middle: a square plate of area A0 grows in area. Right: a cube of volume V0 grows in volume. Dashed outlines show the size before heating; the expansion is exaggerated. at T at T + ΔT L0 ΔL Linear ΔL = L0 α ΔT A0 Area ΔA = A0 β ΔT V0 Volume ΔV = V0 γ ΔT
Figure 2: The three kinds of thermal expansion (exaggerated). Dashed outlines are before heating. , and are the fractional changes in length, area and volume per kelvin.
Material ()Material ()
Aluminium2.5Gold1.4
Brass1.8Iron1.2
Copper1.7Glass (pyrex)0.32
Silver1.9Invar0.09

Metals have : a steel rod lengthens by only about per . Invar (an iron-nickel alloy) barely expands, so it is used for pendulums, measuring tapes and precision instruments. Pyrex glass expands little, so it survives sudden heating.

2.1 Relation between α, β and γ

  1. A square of side heated by has side and area .
  2. , so the squared term is negligible: , i.e. .
  3. A cube: , so .
Why area expansivity is twice the linear expansivity A square of side L grows to side L plus delta L. The new area is the old square plus two strips of area L times delta L and a tiny corner square delta L squared, which is negligible. So the change in area is about 2 L delta L, giving beta equals 2 alpha. For a cube, three slabs give gamma equals 3 alpha. L2 LΔL LΔL (ΔL)2 ≈ 0 L ΔL (L + ΔL)2 = L2 + 2LΔL + (ΔL)2 ΔA ≈ 2LΔL = 2L2αΔT β = ΔA/(AΔT) = 2α Cube, same idea: ΔV ≈ 3L2ΔL ⇒ γ = 3α
Figure 3: The extra area is two strips plus a corner that is negligible because . Hence and, for volume, .
★ Must learn

For an isotropic solid: , , i.e. . For an anisotropic crystal with different expansivities along three axes: and .

3. Consequences: Holes, Cavities and Density

  • A hole expands like the material around it. A hole in a plate, the bore of a ring or the cavity of a hollow sphere grows on heating exactly as if it were filled with the same material. So a ring can be heated to slip over a slightly larger rod (shrink fitting), and a tight metal lid on a glass jar loosens in hot water.
  • Density falls on heating because the mass is unchanged while the volume grows: .
  • Hollow and solid spheres of the same material and outer radius expand equally in outer size.
A hole in a heated plate expands like the plate material A square plate with a circular hole before heating, dashed, and after heating, larger and solid. The hole also becomes larger, as if it were filled with the plate material. Its diameter becomes d0 times one plus alpha delta T. hole grows too The hole expands as if it were made of the plate material: d = d0(1 + αΔT) Same for the cavity of a hollow sphere: V = V0(1 + γΔT), γ of the shell material.
Figure 4: Heating is a uniform photographic enlargement (exaggerated here): every length, including the diameter of a hole, grows by the same factor . This is how a tight metal lid is loosened with hot water.

4. Expansion of Liquids: Real and Apparent

A liquid has no fixed shape, so only its volume expansion is defined. Liquids expand more than solids ( to ). A liquid is always heated in a vessel that also expands, so what we observe is not the full story.

Real and apparent expansion of a liquid in a flask Three flasks with a liquid in a graduated neck. At the start the level is at a mark. Just after heating, the glass expands first and the level falls slightly. Later the liquid expands more than the glass and the level rises above the mark. The observed rise is the apparent expansion. start level at mark just heated vessel expands first: level falls later liquid expands more: level rises observed (apparent) rise = real expansion of liquid − expansion of vessel
Figure 5: A heated liquid first seems to shrink (the vessel warms and expands first), then rises. What we see is the apparent expansion: .
★ Must learn

Real expansion is the actual increase in volume of the liquid; apparent expansion is the increase seen against the vessel's markings. If the vessel is full, the volume that overflows is . If nothing overflows; if is larger, the level falls.

Substance ()Substance ()
Alcohol (ethyl)110Glass (ordinary)2.5
Paraffin58.8Glass (pyrex)1.0
Water20.7Iron3.55
Mercury18.2Aluminium7.0
Exam Trick

Constant empty volume inside a vessel. If a glass vessel of volume holds mercury of volume and the space above the mercury must stay the same at every temperature, the two expansions must be equal: , so . The same idea fixes a constant difference in length between two rods: .

5. Anomalous Expansion of Water

Water behaves unusually between and : on heating, it contracts. Its density is maximum (about ) at about ; above it expands like other liquids. On freezing, water expands by about 9%, which is why ice floats and why water pipes burst in winter.

Anomalous expansion of water: density against temperature from 0 to 12 degrees Celsius Graph of the density of water against temperature. From 0 to about 4 degrees Celsius the density rises, meaning water contracts on heating; it is maximum, about 999.97 kilograms per cubic metre, at about 4 degrees; above 4 degrees the density falls as water expands normally. T (°C) ρ (kg m-3) 0 2 4 6 8 10 12 999.5 999.7 999.9 1000.0 maximum density 999.97 at 4.0 °C 0 → 4 °C: contracts above 4 °C: expands
Figure 6: Water is densest at about (curve from the Kell equation). Between and it contracts on heating (); above it expands normally. Volume of a fixed mass is least at .

Why lakes freeze from the top. As a lake cools, the cooler surface water is denser and sinks until the whole lake reaches . Below the surface water becomes lighter and stays on top, cools to and freezes. Ice is a poor conductor, so the water underneath stays at about and aquatic life survives.

Temperature layers in a frozen lake A lake in winter. The air above is at minus 10 degrees Celsius. A layer of ice floats on top with its lower surface at 0 degrees. Below it the water temperature increases with depth through 1, 2 and 3 degrees to 4 degrees at the bottom, where the densest water collects. air at −10 °C ice (floats: less dense), 0 °C at its lower surface 1 °C 2 °C 3 °C 4 °C (densest water) fish survive in the 4 °C water at the bottom
Figure 7: Water at is densest and sinks; colder water and ice float. Ice, a poor conductor, insulates the water below, so lakes freeze from the top down and aquatic life survives.
Quick Recall: tap to check
At what temperature is the volume of a given mass of water least?
About .
What is for water between and ?
Negative: water contracts on heating in this range.
Why does a glass bottle full of water crack in a freezer?
Water expands by about 9% on freezing.

6. Expansion of Gases

Gases expand far more than solids and liquids, and their expansion depends strongly on pressure, so it is quoted at constant pressure. For an ideal gas ; at constant , (Charles's law), so

At this is , hundreds of times larger than for solids, and it decreases as temperature rises.

Volume of a gas against temperature at constant pressure Graph of volume against Celsius temperature for three samples of gas at constant pressure. Each is a straight line; extended backwards, dashed, all meet the temperature axis at minus 273.15 degrees Celsius, absolute zero. t (°C) V −273.15 0 100 ← all lines meet at absolute zero three samples of gas at constant pressure
Figure 8: At constant pressure (Charles's law), so : about at , much larger than for solids or liquids, and it depends on temperature.

7. Applications of Thermal Expansion

7.1 Bimetallic strip

Two metals with different (say brass and iron) are riveted or welded along their length. On heating, brass expands more, so the strip bends with brass on the convex side. On cooling it bends the other way. For strips of thickness each, the radius of curvature is . Used in thermostats (electric irons, ovens), fire alarms, car indicator flashers and dial thermometers.

Bimetallic strip of brass and iron bending on heating Left: a strip of brass bonded to iron, clamped at one end, is straight at room temperature. Right: when heated it bends into an arc with the brass, which expands more, on the outer convex side. The radius of curvature equals the strip thickness divided by the difference in expansivities times the temperature rise. brass (larger α) iron (smaller α) at room temperature: straight heated: bends brass on the convex (outer) side cooled below room temperature it bends the other way (brass inside) radius R = d / [(α1 − α2)ΔT], d = thickness of each strip
Figure 9: A bimetallic strip bends because the two metals expand by different amounts (curvature exaggerated). The metal with the larger is on the outside of the curve. Used in thermostats, fire alarms and flashers.

7.2 Pendulum clocks

  1. Period , so .
  2. A longer period means fewer oscillations per day: in summer the clock loses time; in winter it gains.
  3. Time lost or gained in a time : ; per day, .
Effect of temperature on a pendulum clock A pendulum hangs from a fixed support. When heated, its length grows from L to L times one plus alpha delta theta, shown as a longer pendulum. The time period, proportional to the square root of length, increases by the fraction one half alpha delta theta, so the clock runs slow in summer and fast in winter. L → L(1 + αΔθ) T = 2π√(L/g) ∝ √L ΔT/T = ½ αΔθ hotter: longer, slower → loses time colder: shorter, faster → gains time time lost per day = ½ αΔθ × 86 400 s
Figure 10: A metal pendulum lengthens on heating, so its period grows by the fraction and the clock loses time (drawn exaggerated). Invar pendulums ( tiny) keep good time.

7.3 Measuring scales

A metal scale is correct at the temperature at which it was calibrated. At a higher temperature each division is longer, so the scale reads less than the true length: true length reading , where is for the scale and is measured from the calibration temperature. If the object also expands, use the difference of expansivities.

7.4 Everyday examples

  • Gaps are left between rails and in bridges (expansion joints); telephone and power lines sag more in summer.
  • Thick glass tumblers crack when hot water is poured in: the inside expands before the outside. Pyrex, with small , does not.
  • Platinum is sealed into glass because their values are nearly equal.
  • Rivets are put in red-hot: on cooling they contract and grip the plates tightly. Iron tyres are heated before fitting on wooden wheels.

8. Thermal Stress

If a rod is fixed between rigid walls and heated, it cannot expand. The walls compress it by exactly the length it wanted to gain, , so its strain is and

The stress does not depend on the length of the rod. On cooling a clamped rod, the stress is tensile. Thermal stress is why rails buckle in heat waves if expansion gaps are too small.

Thermal stress in a rod held between rigid walls, and the expansion gap in railway tracks Left: a rod clamped between two rigid walls is heated. It cannot expand, so it pushes on the walls and the walls push back with force Y A alpha delta T; the rod carries a compressive stress Y alpha delta T. Right: two rails with a small gap between them that leaves room for expansion. rod heated by ΔT rod pushes on the walls walls push back: F = YAαΔT stress = Y α ΔT (compressive) gap rails: gaps allow expansion
Figure 11: If expansion is prevented, the body is strained by and a thermal stress appears, whatever its length. Gaps in rails and bridges, and loops in pipelines, avoid this.
JEE Advanced

Temperature-dependent : gives . Two rods in series between walls (lengths , , same area): total free expansion must be cancelled, and the same force acts in both: . Moment of inertia of a heated body: , so , and a freely spinning disc slows down ( constant): .

Flowchart for thermal expansion problems Decision flowchart. If expansion is prevented, use thermal stress. If a liquid is in a vessel, use apparent expansion. If a clock or a measuring scale is involved, use the time-period or scale correction. Otherwise use the basic expansion formulas for length, area, volume and density. yes no yes no yes no Thermal expansion problem Is the expansion prevented? Thermal stress Y α ΔT force Y A α ΔT Liquid in a vessel? γapp = γliq − γvessel overflow = V γapp ΔT Time-keeping or scale? clock: ΔT/T = ½ α Δθ scale: true = reading(1 + αs Δθ) L = L0(1 + α ΔT), A = A0(1 + 2α ΔT) V = V0(1 + 3α ΔT), ρ = ρ0(1 − γ ΔT)
Figure 12: Four problem types cover almost every thermal expansion question. Identify which one before choosing a formula.
Mind map of thermal expansion Mind map with thermal expansion at the centre and branches for solids, the cause of expansion, liquids, the anomalous expansion of water, gases and applications, each with key formulas. Thermal Expansion Solids ΔL = L0 α ΔT β = 2α, γ = 3α holes expand too Cause asymmetric U(r) well mean spacing grows with T α ~ 10-5 K-1 for metals Liquids only γ is defined γr = γa + γv ρ = ρ0(1 − γΔT) Water anomaly contracts 0 → 4 °C densest at 4 °C lakes freeze from top Gases γ = 1/T at constant p 3.66 × 10-3 K-1 at 0 °C V ∝ T (Charles) Applications bimetal strip, thermostat clock: loses ½αΔθ per s stress YαΔT, rail gaps
Figure 13: Mind map of thermal expansion for quick revision.

9. Solved Examples

Solved Example 1
An aluminium rod is long at . Find its length at . ()
Solution:

.

Answer: (it grows by ).

Solved Example 2
A blacksmith fixes an iron ring on the rim of a wooden wheel. At the diameters of the rim and the ring are and . To what temperature must the ring be heated to fit the rim? ()
Solution:

The ring's diameter must grow by : , so .

Answer: .

Solved Example 3
A hole is drilled in a copper sheet. Its diameter is at . What is its diameter at ? ()
Solution:

The hole expands like copper: .

Answer: (it increases).

Solved Example 4
A brass wire long at is held taut with little tension between two rigid supports. If it is cooled to , what is the tension? (Diameter , , )
Solution:

The wire wants to shorten by but cannot: strain , so .

.

Answer: (tension; independent of length).

Solved Example 5
A steel rod is clamped between two rigid walls at room temperature and heated by . Find the thermal stress. (, )
Solution:

Stress .

Answer: , compressive.

Solved Example 6
A pendulum clock with a steel pendulum () keeps correct time at . How many seconds does it lose or gain per day at ?
Solution:

.

Per day: .

Answer: it loses about per day (period longer, clock slow).

Solved Example 7
A glass flask of volume is completely filled with mercury at . How much mercury overflows when both are heated to ? (, )
Solution:

Overflow .

Answer: .

Solved Example 8
The density of mercury is at . Find its density at . ()
Solution:

.

Answer: .

Solved Example 9
A steel scale is correct at . A length measured with it at reads . What is the true length? ()
Solution:

At each division is longer by the factor , so the scale reads low: true .

Answer: .

Solved Example 10
A bimetallic strip is made of brass () and iron () strips, each thick. Find its radius of curvature when heated by .
Solution:

.

Answer: , with brass on the outer side.

Solved Example 11
The coefficient of linear expansion of a solid is . Its coefficient of volume expansion is
(A)
(B)
(C)
(D)
Solution:

Answer: (C). For an isotropic solid .

Solved Example 12
Water at is heated to . Its volume
(A) increases steadily
(B) decreases steadily
(C) first decreases, then increases
(D) first increases, then decreases
Solution:

Answer: (C). Water contracts from to (volume least at ) and then expands.

Solved Example 13
Find the coefficient of volume expansion of an ideal gas at constant pressure at .
Solution:

.

Answer: .

Practice Questions
  1. A steel rail () is laid at . What gap is needed for ?Answer:
  2. A metal plate's area grows by when heated by . Find .Answer:
  3. By what percentage does the density of a solid () fall when heated by ?Answer: about
  4. An iron rod and a copper rod must differ in length by at all temperatures. Find their lengths. (, , both )Answer: iron , copper
  5. A clock with a brass pendulum () is correct at . Does it gain or lose at , and by how much per day?Answer: gains about
  6. Why does a thick glass tumbler crack when boiling water is poured into it?Answer: The inner surface expands before the outer; the uneven expansion sets up stresses
  7. A liquid has and is in a vessel with . Find its apparent expansivity.Answer:

Common Mistakes to Avoid

Watch out
  • Thinking a hole in a plate shrinks on heating. It expands, like the material around it.
  • Using for a liquid. Liquids have only ; is not defined for them.
  • Forgetting the vessel: the observed (apparent) expansion is .
  • Saying a pendulum clock gains time in summer. The pendulum lengthens, so the clock loses time.
  • Writing thermal stress as : the stress is independent of length.
  • Assuming water always expands on heating; between and it contracts.
  • Putting the metal with the larger on the concave side of a heated bimetallic strip; it is on the convex side.
  • Taking of a gas as a constant; at constant pressure it is and falls as rises.

Frequently Asked Questions

What is thermal expansion?

Thermal expansion is the increase in length, area or volume of a body when its temperature rises. For a small temperature change the fractional change is proportional to the temperature change, with coefficients (length), (area) and (volume).

What is the relation between alpha, beta and gamma?

For an isotropic solid the area coefficient is twice and the volume coefficient three times the linear coefficient, so . It follows from squaring or cubing and dropping small terms.

Why do solids expand on heating?

The potential energy curve between two atoms is steeper on the compression side than on the stretching side. When atoms vibrate with more energy at higher temperature, the midpoint of their vibration shifts to a larger separation, so the average spacing increases.

What is the anomalous expansion of water?

Between and water contracts when heated instead of expanding, so its density is maximum at about . Because of this, lakes freeze from the top and the water at the bottom stays near , allowing fish to survive.

What is the difference between real and apparent expansion of a liquid?

Real expansion is the actual increase in volume of the liquid. Apparent expansion is what is observed against the markings of the vessel, which also expands. .

Why does a pendulum clock lose time in summer?

Heat lengthens the metal pendulum, and the time period is proportional to the square root of the length. A longer period means fewer ticks per day, so the clock runs slow. The fractional change in period is for a temperature rise .

How is thermal expansion asked in NEET?

NEET asks about the ratio , expansion of holes, the anomalous expansion of water, bimetallic strips and simple numericals on the change in length, area, volume or density. Thermal stress also appears with Young's modulus.

Which thermal expansion problems are common in JEE Main?

JEE Main uses pendulum clocks losing or gaining time, apparent expansion and overflow of liquids, thermal stress and force in clamped rods, rods with a constant length difference, scale corrections and the change in moment of inertia or angular speed on heating.

Previous year questions on Thermal Expansion

5 questions from past papers, each with a step-by-step solution.

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