JEE Main2019Chemistry
Q.
Consider the hydrated ions of Ti2+, V2+, Ti3+, and Sc3+. The correct order of their spin-only magnetic moments is :
- A
Sc3+< Ti3+< Ti2+< V2+
- B
Ti3+< Ti2+< Sc3+< V2+
- C
Sc3+< Ti3+< V2+< Ti2+
- D
V2+< Ti2+< Ti3+< Sc3+
Solution
Electronic configuration of the given transition metal ions are
Sc3+ (Z = 21) 1s22s22p63s23p6
Ti2+ (Z = 22) 1s22s22p63s23p63d2
Ti3+ (Z = 22) 1s22s22p63s23p63d1
V2+ (Z = 23) 1s22s22p63s23p63d3
Magnetic moment is directly proportional to the number of unpaired electrons. So the correct increasing order of magnetic moment is
Sc3+ < Ti3+ < Ti2+ < V2+
0 1 2 3 unpaired electrons
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