Mass-energy and nuclear binding energy explain why a nucleus holds together and where nuclear energy comes from. A nucleus always weighs less than its separate protons and neutrons. This missing mass, the mass defect Δm, is stored as binding energy Δmc2, with 1u=931.5MeV. Binding energy per nucleon peaks near A=56 at about 8.8MeV, so both fission and fusion release energy. Mass-energy and nuclear binding energy are tested every year in JEE Main and NEET.
On this page1The nucleus2Isotopes, isobars, isotones3Atomic mass unit4Size and density5Mass-energy equivalence6Mass defect7Binding energy8BE per nucleon curve9Q value10Liquid drop model
Key Formulas - Quick Reference
Notation ZAX: Z protons, N=A−Z neutrons, A nucleons
★ Must learn1u=121 mass of a 12C atom =1.6605×10−27kg=931.5MeV/c2
★ Must learnNuclear radius R=R0A1/3, R0≈1.2fm(1fm=10−15m); density ρ=4πR033mu≈2.3×1017kg m−3, the same for all nuclei
Mass-energy equivalence: E=mc2; 1kg≡9×1016J
★ Must learnMass defect Δm=Zmp+Nmn−Mnucleus=ZmH+Nmn−Matom
★ Must learnBinding energy BE=Δmc2=Δm(in u)×931.5MeV; stability grows with ABE
★ Must learnQ value: Q=(∑minitial−∑mfinal)c2=∑BEfinal−∑BEinitial
1. The Nucleus and Its Constituents
Rutherford's α-scattering experiment (1911) showed that the positive charge and almost all the mass of an atom sit in a tiny central nucleus. The nucleus is made of two kinds of particles, together called nucleons:
Particle
Charge
Mass (u)
Mass (kg)
Discovered
Proton p
+e
1.007276
1.6726×10−27
Rutherford (1919), as the hydrogen nucleus
Neutron n
0
1.008665
1.6749×10−27
James Chadwick (1932)
Electron e
−e
0.000549
9.109×10−31
J. J. Thomson (1897)
The neutron is slightly heavier than the proton (mn−mp≈1.29MeV/c2), which is why a free neutron can decay into a proton. A nucleus is labelled by two whole numbers:
Atomic number Z: the number of protons. It fixes the chemical element.
Mass number A: the total number of nucleons, A=Z+N, where N is the neutron number. A is the whole number nearest to the atomic mass in u.
Figure 1: A nucleus is about 105 times smaller than its atom but carries almost all its mass. The symbol ZAX gives the mass number A (nucleons) and atomic number Z (protons); the neutron number is N=A−Z.
The nucleus is written ZAX (some books write ZXA). For example 79197Au has 79 protons and 197−79=118 neutrons. A particular nucleus with given Z and N is called a nuclide.
1.1 Isotopes, isobars and isotones
Name
Same
Different
Examples
Isotopes
Z (same element)
N and A
11H, 12H, 13H; 1735Cl, 1737Cl
Isobars
A
Z and N
13H, 23He; 614C, 714N
Isotones
N
Z and A
13H, 24He (N=2); 614C, 816O (N=8)
Isodiaphers
N−Z
Z, A
92238U and 90234Th (N−Z=54): parent and daughter in α-decay
Figure 2: A corner of the chart of nuclides. Isotopes lie in a column (same Z), isotones in a row (same N) and isobars on a diagonal (same A=Z+N). Only the peach cells are stable.
Exam Trick
Match the letter to what stays the same. Isotopes: same protons. Isotones: same neutrons. Isobars: same mass number A. Isotopes are chemically identical because chemistry depends only on Z.
2. Atomic Mass Unit and Atomic Masses
Nuclear masses are tiny in kilograms, so they are measured in the atomic mass unit (u), defined from carbon-12:
1u=12mass of one 12C atom=12×NA12×10−3kg mol−1=1.660539×10−27kg
Its energy equivalent is 1u×c2=1.4924×10−10J=931.494MeV. Exam problems use 931.5MeV per u (sometimes 931MeV).
Tables list atomic masses (nucleus plus Z electrons), because these are what mass spectrometers measure. On this scale mp=1.007276u, mn=1.008665u, and the hydrogen atom mH=1.007825u. The atomic mass of an element in the periodic table (for example 35.45u for chlorine) is an average over its isotopes weighted by their abundance: 0.758×34.97+0.242×36.97=35.45u.
Key idea
The nucleus is labelled by Z and A; masses are in u, and every u of mass is worth 931.5MeV of energy.
3. Size and Density of the Nucleus
Scattering of fast electrons and α-particles shows that nuclei are roughly spherical, with a radius that grows as the cube root of the mass number:
R=R0A1/3,R0≈1.2fm=1.2×10−15m
The femtometre (fermi), 1fm=10−15m, is the natural unit. Different experiments give R0 between 1.1 and 1.3fm; NCERT uses 1.2fm. So volume ∝R3∝A.
Figure 3: R=R0A1/3 with R0=1.2fm (orange) and 1.1fm (dashed). Going from 4He to 238U multiplies A by about 60 but R only by 601/3≈3.9 (1.90 to 7.44 fm).
3.1 Nuclear density is the same for all nuclei
Mass of a nucleus ≈Amu (each nucleon weighs about 1u).
Figure 4: Nuclei drawn to scale (R0=1.2fm). The volume 34πR03A grows exactly as the mass Amu, so all nuclei have the same density ρ=4πR033mu=2.29×1017kg m−3.
A cancels, so all nuclei, from helium to uranium, have the same density. This is about 1014 times the density of water: a teaspoon of nuclear matter would weigh some billion tonnes. Neutron stars are made of matter at this density. A constant density is what we expect of a liquid drop: nucleons are packed like molecules in a drop, which is the idea behind the liquid drop model (Section 9).
Quick Recall: tap to checkBy what factor does the radius grow from 27Al to 216Po?
(27216)1/3=81/3=2.
Does nuclear density depend on the mass number?
No. Mass ∝A and volume ∝A, so ρ=4πR033mu is the same for every nucleus.
What is 1fm?
10−15m, the natural unit of nuclear size.
4. Mass-Energy Equivalence
Einstein's special relativity (1905) showed that mass is a form of energy. A body of mass m at rest has rest-mass energy:
E=mc2
In any process the total energy, rest-mass energy included, is conserved. When energy is released, the total rest mass of the system falls by Δm=c2ΔE.
One kilogram is equivalent to 1×(3×108)2=9×1016J. In chemical reactions the mass change is only about 10−9 of the mass and cannot be measured, so chemistry uses "conservation of mass". In nuclear reactions about 0.1% of the mass changes into energy, and the change is easily seen. Pair annihilation (e−+e+→2γ, each photon 0.511MeV) turns rest mass completely into radiation, and pair production does the reverse.
Figure 5: E=mc2 with nothing hidden. The electron's rest energy is mec2=0.00054858×931.494=0.511MeV. Annihilation turns the whole rest mass of e− and e+ into two γ-rays; pair production needs a photon of at least 2mec2=1.022MeV.
Exam Trick
Never convert to joules unless asked. Keep masses in u and multiply by 931.5 to get MeV directly. Then 1MeV=1.6×10−13J if a joule answer is needed.
5. Mass Defect
Adding up the masses of the protons and neutrons in a nucleus always gives more than the measured mass of the nucleus. The difference is the mass defect.
Δm=[Zmp+(A−Z)mn]−Mnucleus
Since Mnucleus=Matom−Zme (neglecting the tiny electron binding energies), and mp+me=mH, the same result in terms of atomic masses is
Δm=[ZmH+(A−Z)mn]−Matom
Use mH with atomic masses and the electron masses cancel automatically.
Figure 6: The mass defect of 4He: 2mp+2mn=4.031883u but the nucleus has m=4.001506u. The missing Δm=0.03038u is the binding energy Δmc2=28.3MeV (the axis is broken to show the small difference).
For helium-4: 2mH+2mn=2(1.007825)+2(1.008665)=4.032980u, while M(4He)=4.002603u, so Δm=0.030377u. The nucleus is lighter because energy was given out when it formed: the mass defect is the mass of that energy.
6. Binding Energy
The binding energy of a nucleus is the minimum energy needed to separate it completely into its free protons and neutrons (at rest, far apart). Equally, it is the energy released when the free nucleons combine to form the nucleus.
BE=Δmc2=Δm(in u)×931.5MeV
For 4He: BE=0.030377×931.5=28.3MeV.
Figure 7: Binding energy two ways. It is the energy needed to pull a nucleus apart into free nucleons, and also the energy given out when those nucleons come together. Both equal Δmc2.
The binding energy is the depth of the energy well in which the nucleons sit. The larger it is, the harder the nucleus is to break up. A few useful values:
Nucleus
Δm (u)
BE (MeV)
ABE (MeV)
12H (deuteron)
0.002388
2.22
1.11
24He
0.030377
28.30
7.07
612C
0.098940
92.16
7.68
816O
0.137005
127.62
7.98
2656Fe
0.528463
492.3
8.79
92235U
1.915058
1783.9
7.59
92238U
1.934194
1801.7
7.57
6.1 Separation energy
The energy needed to remove just one nucleon is the separation energy. Removing a neutron from ZAX leaves ZA−1X, so
Sn=[m(ZA−1X)+mn−m(ZAX)]c2=BE(ZAX)−BE(ZA−1X)
and for a proton Sp=[m(Z−1A−1Y)+mH−m(ZAX)]c2. For 17O, Sn=4.14MeV, much less than the 7.75MeV average, because the odd neutron is loosely bound outside the tightly bound 16O core.
Binding energy (BE)
Energy to pull the whole nucleus apart into A free nucleons. Grows with size: 28.3MeV for He-4, 1802MeV for U-238.
Binding energy per nucleon (BE/A)
Average energy to remove one nucleon. It measures stability: Fe-56 (8.79MeV) is more stable than U-238 (7.57MeV) even though its total BE is far smaller.
Quick Recall: tap to checkWhy is a nucleus lighter than its free nucleons?
Energy BE was released when it formed; the lost mass is c2BE.
Why use mH rather than mp with atomic masses?
mH=mp+me includes one electron per proton, so the Z electrons in Matom cancel.
Which is the better measure of stability: BE or BE/A?
ABE. A bigger nucleus has a bigger total BE simply because it has more nucleons.
7. Binding Energy per Nucleon Curve
Plotting ABE against A for all stable nuclei gives one of the most important graphs in physics.
Figure 8: Binding energy per nucleon from measured masses (grey dots: all 288 naturally occurring nuclides; orange: the most abundant isotope of each element). The curve peaks at 56Fe (8.79 MeV), so joining light nuclei (fusion) or splitting heavy ones (fission) both release energy.
7.1 Features of the curve
Light nuclei (A<20):ABE is small and rises steeply, with sharp peaks for 4He, 12C, 16O, 20Ne (nuclei built of "α-particle units").
Middle nuclei (30<A<170): the curve is nearly flat at 8.0 to 8.8MeV. The maximum is about 8.8MeV near A=56 to 62 (56Fe: 8.79MeV; 62Ni: 8.795MeV is the true maximum). These are the most stable nuclei.
Heavy nuclei (A>170):ABE falls slowly, to 7.6MeV for uranium, because Coulomb repulsion between many protons grows.
Figure 9: Light nuclei are irregular. 4He (7.07 MeV per nucleon) is far more tightly bound than its neighbours 3He (2.57) and 6Li (5.33); that is why heavy nuclei emit α-particles rather than single nucleons.
7.2 What the curve tells us
Fission: a heavy nucleus (ABE≈7.6MeV) that splits into two middle nuclei (≈8.5MeV) gains about 0.9MeV per nucleon: roughly 0.9×236≈200MeV per fission.
Fusion: light nuclei joining into a heavier one climb the steep left side, releasing even more energy per nucleon (D-T fusion: 3.5MeV per nucleon).
Short-range force: the flat middle shows that each nucleon feels only its near neighbours. If every nucleon attracted every other, BE would grow as A2 and ABE as A. This saturation is taken up in the next concept, Nuclear Forces and Nuclear Energy.
Figure 10: Total binding energy grows almost in proportion to A (about 8MeV per nucleon), not as the number of pairs 2A(A−1). Each nucleon attracts only its near neighbours: the nuclear force is short-range and saturates.
Exam Trick
Energy released = (BE after) − (BE before). When binding energies per nucleon are given, compute ∑A⋅ABE for products minus the same for reactants. Example: a nucleus with A=240, ABE=7.6MeV splits into two with A=120, ABE=8.5MeV: Q=240(8.5−7.6)=216MeV.
Key idea
The higher the binding energy per nucleon, the more stable the nucleus. Energy is released whenever nucleons move to nuclei with higher ABE: towards A≈56 from either side.
8. Q Value of a Nuclear Reaction
For any nuclear reaction or decay a+X→Y+b, the Q value is the energy released:
Q=[(ma+mX)−(mY+mb)]c2=(KY+Kb)−(Ka+KX)
Because the number of protons and neutrons does not change, Q also equals (total BE of products) − (total BE of reactants). Q>0: exothermic, rest mass turns into kinetic energy. Q<0: endothermic, needs energy input.
Figure 11: Q=(∑minitial−∑mfinal)c2 (levels not to scale). D-T fusion: Q=+17.6MeV, rest mass turns into kinetic energy. 14N(α,p)17O: Q=−1.19MeV, kinetic energy turns into rest mass, and momentum conservation raises the threshold to ∣Q∣(1+mNmα)=1.53MeV.
Charge and nucleon number balance, so atomic masses can be used on both sides and the electrons cancel. The one exception is β+ decay, where 2me must be subtracted (see Radioactivity). Example: 12H+13H→24He+n gives Q=(2.014102+3.016049−4.002603−1.008665)×931.5=17.6MeV.
JEE Advanced
Threshold energy of an endothermic reaction. For a+X→Y+b with Q<0 and X at rest, supplying just ∣Q∣ is not enough: the centre of mass must keep moving, so part of the projectile's kinetic energy stays as kinetic energy. The minimum (threshold) kinetic energy of the projectile is
Kth=∣Q∣(1+mXma)
For Rutherford's reaction 14N(α,p)17O, Q=1.19MeV but Kth=1.19(1+144)=1.53MeV (Figure 11).
Quick Recall: tap to checkWhat does a positive Q value mean?
Energy is released: the products have less rest mass and more kinetic energy than the reactants.
Can Q be found from binding energies alone?
Yes: Q=∑BEproducts−∑BEreactants, since the nucleons are the same on both sides.
In which decay must you subtract 2me when using atomic masses?
β+ decay.
9. Liquid Drop Model and Semi-empirical Mass Formula
The constant density and the saturation of binding energy suggest treating the nucleus like a drop of incompressible liquid. Each effect on the binding energy then has a simple origin.
JEE Advanced
Bethe-Weizsäcker formula.
BE=avA−asA2/3−acA1/3Z(Z−1)−aaA(N−Z)2±δ
Volume termavA (av≈15.8MeV): each nucleon bonds with its neighbours, so BE∝A.
Surface term−asA2/3 (as≈17.8MeV): surface nucleons have fewer neighbours; surface area ∝R2∝A2/3. Most important for light nuclei.
Coulomb term−acA1/3Z(Z−1) (ac≈0.71MeV): proton-proton repulsion; energy of a charged sphere ∝RQ2. Most important for heavy nuclei.
Asymmetry term−aaA(N−Z)2 (aa≈23.7MeV): a quantum effect favouring N=Z.
Pairing termδ: even-even nuclei are extra bound, odd-odd less.
With these five terms the formula reproduces measured binding energies of heavy nuclei to within about 1%. For 56Fe it gives 8.85MeV per nucleon against the measured 8.79MeV.
Figure 12: The semi-empirical (liquid drop) formula term by term, per nucleon, with Z set to its most stable value. Surface loss hurts light nuclei, Coulomb repulsion hurts heavy ones; the peak between them is near A≈60. Black dots are measured values.
Key idea
Surface loss pulls ABE down for light nuclei, Coulomb repulsion pulls it down for heavy nuclei; the peak between them is near iron.
10. Problem-Solving Map and Revision
Use the flowchart to pick the correct masses, then the mind map to revise the concept.
Figure 13: Choosing the right masses. Using mH with atomic masses makes the electrons cancel automatically.Figure 14: Mind map of this concept. Read the left column, then the right; cover a branch, recall its three points, then check.
11. Solved Examples
Solved Example 1
Find the density of nuclear matter, taking R0=1.1×10−15m and mp=1.67×10−27kg. Repeat with R0=1.2fm.
Solution:
ρ=34πR03AAmp=4πR033mp, independent of A.
ρ=4×3.14×(1.1×10−15)33×1.67×10−27=3.0×1017kg m−3
With R0=1.2fm the cube is 1.728×10−45 and ρ=2.3×1017kg m−3.
Answer: ρ≈3×1017kg m−3 (R0=1.1fm), 2.3×1017kg m−3 (R0=1.2fm), the same for every nucleus.
Solved Example 2
The radius of a germanium nucleus is measured to be twice the radius of 49Be. How many nucleons are there in the Ge nucleus?
Solution:
R∝A1/3, so ABeAGe=(RBeRGe)3=23=8.
Answer: AGe=8×9=72 nucleons (72Ge).
Solved Example 3
Calculate the energy equivalent of 1g of matter. For how long could it run a 1kW heater?
Solution:
E=mc2=10−3×(3×108)2=9×1013J.
Time =1039×1013=9×1010s≈2850 years.
Answer: 9×1013J (2.5×107kWh), enough for about 2850 years.
Solved Example 4
Find the binding energy and binding energy per nucleon of 816O. Atomic mass of 16O=15.994915u, mH=1.007825u, mn=1.008665u.
Solution:
Δm=8mH+8mn−M=8(1.007825)+8(1.008665)−15.994915
=8.062600+8.069320−15.994915=0.137005u.
BE=0.137005×931.5=127.6MeV; ABE=16127.6.
Answer: BE=127.6MeV, ABE=7.98MeV per nucleon.
Solved Example 5
Calculate the binding energy per nucleon of 2656Fe. Atomic mass =55.934936u.
Solution:
N=30. Δm=26(1.007825)+30(1.008665)−55.934936
=26.203450+30.259950−55.934936=0.528464u.
BE=0.528464×931.5=492.3MeV.
Answer: ABE=56492.3=8.79MeV per nucleon, close to the maximum of the curve.
Solved Example 6
Find the energy needed to remove one neutron from 817O. Atomic masses: 17O=16.999132u, 16O=15.994915u, mn=1.008665u.
Answer: Sn≈4.14MeV, about half the average binding energy per nucleon.
Solved Example 7
A nucleus with mass number 240 and ABE=7.6MeV breaks into two fragments, each with A=120 and ABE=8.5MeV. The energy released is (A) 0.9MeV (B) 108MeV (C) 216MeV (D) 2040MeV
Solution:
Answer: (C).Q=2×120×8.5−240×7.6=2040−1824=216MeV. Option (A) is the gain per nucleon; (D) is the total BE of the fragments.
Solved Example 8
Two deuterons (ABE=1.1MeV) fuse to form 4He (ABE=7.07MeV). The energy released is about (A) 5.97MeV (B) 11.9MeV (C) 23.9MeV (D) 28.3MeV
Solution:
Answer: (C).Q=4×7.07−2×(2×1.1)=28.28−4.4=23.9MeV. Each deuteron has A=2, so its total BE is 2.2MeV.
Solved Example 9
Which of the following pairs are isotones? (A) 614C, 714N (B) 614C, 816O (C) 612C, 614C (D) 13H, 23He
Solution:
Answer: (B).N=14−6=8 and N=16−8=8. (A) and (D) are isobars; (C) are isotopes.
Solved Example 10
An electron and a positron, both nearly at rest, annihilate into two photons. Find the energy and wavelength of each photon (mec2=0.511MeV, hc=1240eV nm).
Solution:
Total momentum is zero, so the two photons fly apart in opposite directions with equal energies. Energy conservation: 2Eγ=2mec2.
Answer: Eγ=0.511MeV each, λ=2.43pm (a γ-ray). One photon alone is impossible: it could not carry away zero momentum.
Solved Example 11
For 14N+4He→17O+1H, find Q and the threshold kinetic energy of the α-particle (nitrogen at rest). Atomic masses: 14N=14.003074, 4He=4.002603, 17O=16.999132, 1H=1.007825u.
Solution:
∑mi=18.005677u, ∑mf=18.006957u, so Δm=−0.001280u and Q=−0.001280×931.5=−1.19MeV.
The binding energies per nucleon of 37Li and 24He are 5.60MeV and 7.07MeV. In the reaction 37Li+11H→224He the energy released is (A) 8.7MeV (B) 17.3MeV (C) 28.3MeV (D) 39.2MeV
Solution:
Answer: (B). The proton has no binding energy. Q=2×4×7.07−7×5.60=56.56−39.20=17.36≈17.3MeV. (A) is the energy per α-particle, (C) is the binding energy of one 4He and (D) that of 7Li.
Practice Questions
How many protons and neutrons are in 92235U?Answer: 92 protons, 143 neutrons
Find the ratio of the radii of 27Al and 125Te.Answer: 3:5
Find the mass defect and binding energy of the deuteron. m(2H)=2.014102u.Answer: 0.002388u; 2.22MeV
Find the binding energy per nucleon of 12C (atomic mass exactly 12u).Answer: Δm=0.098940u, BE=92.2MeV, 7.68MeV per nucleon
How much mass is converted into energy when 1kWh is produced?Answer: 4×10−11kg
Two nuclei have mass numbers in the ratio 1:8. Find the ratio of their nuclear densities.Answer: 1:1
Find Q for 2H+2H→3He+n. Masses: 2.014102, 3.016029, 1.008665u.Answer: 3.27MeV
Common Mistakes to Avoid
Watch out
Mixing atomic and nuclear masses: using mp with an atomic mass leaves Z electron masses uncancelled. Use mH with atomic masses, mp with nuclear masses.
Taking the mass of a nucleon as exactly 1u in binding-energy problems. The whole answer lives in the fourth decimal place; keep all given digits.
Judging stability by total BE. Use ABE: 238U has the larger BE but 56Fe is far more stable.
Writing R∝A or R∝A1/2. It is R∝A1/3, so volume, not radius, is proportional to A.
Thinking heavier nuclei are denser. Nuclear density is the same for all nuclei.
Using 1u=931.5MeV with the mass in kg or grams. Convert to u first, or use E=mc2 in SI units.
Saying mass is 'destroyed' in a nuclear reaction. Rest mass turns into kinetic energy; total energy (and mass-energy) is conserved.
Forgetting that the maximum of the ABE curve is only about 8.8MeV and occurs near A=56, not at uranium or helium.
Frequently Asked Questions
What is mass defect in nuclear physics?
Mass defect is the difference between the total mass of the separate protons and neutrons in a nucleus and the actual mass of the nucleus. The nucleus is always lighter. For helium-4 the mass defect is 0.0304 u, which corresponds to its binding energy of 28.3 MeV.
What is binding energy of a nucleus?
Binding energy is the minimum energy needed to break a nucleus into its free protons and neutrons, or equally the energy released when those nucleons come together. It equals the mass defect times c2, and one atomic mass unit of mass defect gives 931.5 MeV.
Why is binding energy per nucleon a measure of nuclear stability?
Total binding energy grows with the number of nucleons, so it cannot compare nuclei of different sizes. Binding energy per nucleon is the average energy needed to remove one nucleon. The larger it is, the more tightly each nucleon is held and the more stable the nucleus.
Which nucleus is the most stable?
Nuclei near iron and nickel have the highest binding energy per nucleon, about 8.8 MeV. Iron-56 is usually quoted, while nickel-62 is very slightly higher. Energy is released when lighter nuclei fuse or heavier nuclei split, because both move towards this peak.
Why is nuclear density the same for all nuclei?
The mass of a nucleus is proportional to its mass number, and its radius follows R=R0A1/3, so its volume is also proportional to the mass number. The two cancel and every nucleus has a density of about 2.3 times ten to the seventeen kilogram per cubic metre.
What is the value of 1 atomic mass unit in MeV?
One atomic mass unit is one twelfth of the mass of a carbon-12 atom, 1.6605 times ten to the minus 27 kilogram. Its energy equivalent from E=mc2 is 931.494 MeV, usually rounded to 931.5 MeV in calculations.
How is binding energy asked in NEET?
NEET questions ask for the binding energy or mass defect from given masses, compare stability using binding energy per nucleon, use the radius formula R=R0A1/3 and nuclear density, and read the shape of the binding energy per nucleon graph. Remember 931.5 MeV per u.
How is binding energy tested in JEE Main and Advanced?
JEE Main asks mass defect, binding energy per nucleon and energy released from the curve. JEE Advanced adds Q values with atomic masses, separation energies, beta plus mass corrections and questions based on the liquid drop formula and its surface and Coulomb terms.
Previous year questions on Mass-Energy and Nuclear Binding Energy
19 questions from past papers, each with a step-by-step solution.