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JEE Advanced2023Paper 1CHEM-II
Q.

In the scheme given below, X and Y, respectively, are

  1. A

    CrO and Br

  2. B

    MnO and Cl

  3. C

    MnO and Cl

  4. D

    MnSO and HOCl

Solution

Identify the metal halide. The starting halide must give a white precipitate with NaOH and contain a halide ion that can be oxidised to a halogen which turns starch-iodide paper blue. This points to :

So the filtrate Q contains chloride ions.

Formation of X. Manganese(II) hydroxide is oxidised by PbO in acidic medium (analogous to the Mn(II) to permanganate test) to the deep purple permanganate ion: Thus X = MnO.

Formation of Y. Chloride in conc. HSO with MnO(OH) as oxidant gives chlorine gas: Chlorine oxidises iodide on the starch-iodide paper to iodine, giving the characteristic blue colour with starch: .

Hence Y = Cl. Answer: (C).

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