In the scheme given below, X and Y, respectively, are

- A
CrO and Br
- B
MnO and Cl
- C
MnO and Cl
- D
MnSO and HOCl
Identify the metal halide. The starting halide must give a white precipitate with NaOH and contain a halide ion that can be oxidised to a halogen which turns starch-iodide paper blue. This points to :
So the filtrate Q contains chloride ions.
Formation of X. Manganese(II) hydroxide is oxidised by PbO in acidic medium (analogous to the Mn(II) to permanganate test) to the deep purple permanganate ion: Thus X = MnO.
Formation of Y. Chloride in conc. HSO with MnO(OH) as oxidant gives chlorine gas: Chlorine oxidises iodide on the starch-iodide paper to iodine, giving the characteristic blue colour with starch: .
Hence Y = Cl. Answer: (C).
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