JEE Advanced2023Paper 1CHEM-II
Q.
Plotting against for aqueous solutions of a monobasic weak acid (HX) resulted in a straight line with y-axis intercept of and slope of . The ratio is
[ = molar conductivity, = limiting molar conductivity, = molar concentration, = dissociation constant of HX]
- A
- B
- C
- D
Solution
Degree of dissociation. For the weak acid, .
Ostwald dilution law. , which rearranges to . Substituting :
Dividing both sides by and rearranging gives the standard linear form:
Identify slope and intercept. Plotting (y-axis) against (x-axis):
Ratio. .
Answer: (A).
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