Fundamentholfundamenthol
JEE Advanced2025Paper 1CHEM-II
Q.

The pair(s) of diamagnetic ions is(are)

  1. A

    La, Ce

  2. B

    Yb, Lu

  3. C

    La, Ce

  4. D

    Yb, Lu

Solution

Write each ion's electronic configuration beyond [Xe] and check for unpaired electrons:

La: [Xe] 4f → diamagnetic. Ce: [Xe] 4f → diamagnetic. Pair (A) is diamagnetic.

Yb: [Xe] 4f → diamagnetic. Lu: [Xe] 4f → diamagnetic. Pair (B) is diamagnetic.

La: [Xe] 5d → paramagnetic. Ce: [Xe] 4f → paramagnetic. Pair (C) is not diamagnetic.

Yb: [Xe] 4f → paramagnetic. Lu: [Xe] 4f 5d → paramagnetic. Pair (D) is not diamagnetic.

Diamagnetic pairs are (A) and (B).

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