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JEE Main 2025 Apr 4 Shift 1, Chemistry Q3: Molecular Orbital Theory

JEE Main2025Apr 4, Shift 1Chemistry
Q.

Which of the following molecules(s) show/s paramagnetic behavior ?

(A)   (B)   (C)   (D)   (E)

Choose the correct answer from the options given below :

  1. A

    B only

  2. B

    A & C only

  3. C

    A & E only

  4. D

    A & D only

Solution

A species is paramagnetic when its MO configuration contains one or more unpaired electrons.

Counting unpaired electrons from molecular orbital theory:

MoleculeUnpaired electrons
2 (two singly-filled orbitals)
0
0
2 (analogous to )
0

Only and are paramagnetic, so the correct option is A & D.

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