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JEE Main 2025 Apr 8 Shift 2, Chemistry Q2: Introduction to Mechanism of Organic Reaction

JEE Main2025Apr 8, Shift 2Chemistry
Q.

Match the LIST-I with LIST-II

LIST-ILIST-II
A. CarbocationI. Species that can supply a pair of electrons.
B. C-Free radicalII. Species that can receive a pair of electrons.
C. NucleophileIII. sp hybridized carbon with empty p-orbital.
D. ElectrophileIV. sp/sp hybridized carbon with one unpaired electron.

Choose the correct answer from the options given below:

  1. A

    A-IV, B-II, C-III, D-I

  2. B

    A-II, B-III, C-I, D-IV

  3. C

    A-III, B-IV, C-II, D-I

  4. D

    A-III, B-IV, C-I, D-II

Solution

A carbocation carries an empty p-orbital on an sp hybridised carbon, so A matches III.

A carbon free radical has one unpaired electron on an sp/sp hybridised carbon, so B matches IV.

A nucleophile is, by definition, a species that donates an electron pair, so C matches I.

An electrophile is a species that accepts an electron pair, so D matches II.

Combining these gives A-III, B-IV, C-I, D-II, which is option (4).

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