JEE Main2026Jan 23, Shift 1Chemistry
Q.
Which one of the following graphs accurately represents the plot of partial pressure of CS vs its mole fraction in a mixture of acetone and CS at constant temperature?
- A

- B

- C

- D

Solution
Acetone (CHCOCH) and CS form a mixture that shows positive deviation from Raoult's law: the dipole–dipole interactions in pure acetone are disrupted on mixing with non-polar CS, so molecules escape more readily into the vapour and the observed partial pressure exceeds the ideal value.
for all intermediate compositions, giving a curve that bows upward from the Raoult-law straight line — matching option (1).
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