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JEE Main2026Jan 24, Shift 2Chemistry
Q.

Given below are two statements :

Statement I : There are several conformers for n-butane. Out of those conformers, is the least stable and most stable conformer is

Statement II : As the dihedral angle increases, torsional strain decreases from (X) to (Y).

In the light of the above statements, choose the correct answer from the options given below :

  1. A

    Both Statement I and Statement II are false

  2. B

    Statement I is false but Statement II is true

  3. C

    Statement I is true but Statement II is false

  4. D

    Both Statement I and Statement II are true

Solution

Statement I: For n-butane, the fully eclipsed conformer (methyls at 0°) has the highest torsional and steric strain — least stable; the anti conformer (methyls at 180°) has the lowest strain — most stable. True.

Statement II: Going from the fully eclipsed (0°) to anti (180°) conformer, the dihedral angle increases and torsional strain decreases monotonically (with minor maxima/minima at gauche and eclipsed positions in between). True.

Both statements are correct.

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