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NEET2025Chemistry
Q.

Which of the following statements are true?

A. Unlike Ga that has a very high melting point, Cs has a very low melting point.

B. On Pauling scale, the electronegativity values of N and Cl are not the same.

C. Ar, K, Cl, Ca, and S are all isoelectronic species.

D. The correct order of the first ionization enthalpies of Na, Mg, Al, and Si is Si > Al > Mg > Na.

E. The atomic radius of Cs is greater than that of Li and Rb.

Choose the correct answer from the options given below:

  1. A

    A, B and E only

  2. B

    C and E only

  3. C

    C and D only

  4. D

    A, C and E only

Solution

C is correct: Ar, K, Cl, Ca, S all have 18 electrons, hence isoelectronic.

E is correct: down Group 1, atomic radius increases (Li < Na < K < Rb < Cs), so Cs > Rb > Li.

A is wrong: both Ga and Cs have low melting points (Ga melts near body temperature; Cs near 28 °C).

B is wrong: N and Cl have nearly the same Pauling electronegativity (≈ 3.0).

D is wrong: the actual order has anomalies — Mg > Al because removing an electron from Al breaks a filled 3s; Si > Al but Al < Mg.

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