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JEE Main2026Apr 5, Shift 1Chemistry
Q.

Identify the incorrect statements :

A.

is a stronger base than

B.

can be synthesized by Gabriel phthalimide synthesis.

C.

D

will dissolve in NaOH.


Choose the correct answer from the options given below :

  1. A

    A and D only

  2. B

    A and C only

  3. C

    B and C only

  4. D

    A and B only

Solution

A: In aniline the lone pair on nitrogen is delocalised into the ring, lowering basicity. Benzylamine's nitrogen lone pair is not delocalised, so benzylamine is more basic than aniline. Statement A is correct.

B: Gabriel synthesis works only with reactive alkyl halides (S2); aryl halides do not react with the phthalimide ion. So -anisidine cannot be made by this method. Statement B is incorrect.

C: Hofmann bromamide degradation of an amide shortens the chain by one carbon. From this gives , which is an aliphatic (benzylic) primary amine, not an aromatic amine. Statement C is incorrect.

D: 4-Nitroaniline diazotised at 0C and warmed gives 4-nitrophenol, which is acidic enough to dissolve in NaOH. Statement D is correct.

Incorrect statements: B and C.

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