Identify the incorrect statements :
A.

is a stronger base than

B.

can be synthesized by Gabriel phthalimide synthesis.
C.

D

will dissolve in NaOH.
Choose the correct answer from the options given below :
- A
A and D only
- B
A and C only
- C
B and C only
- D
A and B only
A: In aniline the lone pair on nitrogen is delocalised into the ring, lowering basicity. Benzylamine's nitrogen lone pair is not delocalised, so benzylamine is more basic than aniline. Statement A is correct.
B: Gabriel synthesis works only with reactive alkyl halides (S2); aryl halides do not react with the phthalimide ion. So -anisidine cannot be made by this method. Statement B is incorrect.
C: Hofmann bromamide degradation of an amide shortens the chain by one carbon. From this gives , which is an aliphatic (benzylic) primary amine, not an aromatic amine. Statement C is incorrect.
D: 4-Nitroaniline diazotised at 0C and warmed gives 4-nitrophenol, which is acidic enough to dissolve in NaOH. Statement D is correct.
Incorrect statements: B and C.
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