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NEET2022Chemistry
Q.

Match List-I with List-II

List-I (Hydrides)List-II (Nature)
(a)MgH(i)Electron precise
(b)GeH(ii)Electron deficient
(c)BH(iii)Electron rich
(d)HF(iv)Ionic

Choose the correct answer from the options given below :

  1. A

    (a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)

  2. B

    (a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)

  3. C

    (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)

  4. D

    (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)

Solution

Classify each hydride by the relation between its bonding electrons and the number of bonds it needs.

MgH is a saline (ionic) hydride formed by an active metal, matching (iv).

GeH has just enough electrons to form four two-centre two-electron bonds with no lone pairs, so it is electron precise, matching (i).

BH has fewer valence electrons than required for normal 2c-2e bonds and uses 3c-2e banana bonds, making it electron deficient, matching (ii).

HF has lone pairs on the central atom over and above its bonding electrons, classifying it as electron rich, matching (iii).

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