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NEET 2023, Chemistry Q34: Properties of Ether

NEET2023Chemistry
Q.

Consider the following reaction:

Identify products A and B:

  1. A

    1

  2. B

    2

  3. C

    3

  4. D

    4

Solution

When a mixed ether containing an aryl and alkyl group is cleaved by HI, the alkyl side leaves as the alkyl iodide and the aryl side stays as the phenol — because the C–O bond to the aromatic carbon is much stronger than the bond to the carbon.

Here benzyl phenyl ether cleaves to give benzyl iodide () and phenol ().

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