NEET 2023, Chemistry Q44: Colour, Magnetism And Stability Of Co-ordination Compounds

NEET2023Chemistry

Which complex compound is most stable?

A
$[Co (NH_{3})_{3} (NO_{3})_{3}]$
B
$[CoCl_{2} (en)_{2}] NO_{3}$
C
$[Co (NH_{3})_{6}]_{2} (SO_{4})_{3}$
D
$[Co (NH_{3})_{4} (H_{2} O) Br] (NO_{3})_{2}$

Solution

Ethylenediamine (en) is a bidentate ligand. Complexes containing chelating bidentate ligands enjoy the chelate effect: ring formation gives a large entropic boost that markedly increases stability over similar complexes with monodentate ligands alone.

$[CoCl_{2} (en)_{2}] NO_{3}$ has two en chelate rings around Co, making it the most stable of the four options.

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NEET 2023, Chemistry Q44: Colour, Magnetism And Stability Of Co-ordination Compounds

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