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JEE Main2026Apr 2, Shift 1Chemistry
Q.

Given below are two statements :

Statement (I) : 1,2,3-Trihydroxypropane can be separated from water by simple distillation.

Statement (II) : An azotropic mixture cannot be separated by fractional distillation.

In the light of the above statements, choose the correct answer from the options given below :

  1. A

    Both Statement I and Statement II are true

  2. B

    Both Statement I and Statement II are false

  3. C

    Statement I is true but Statement II is false

  4. D

    Statement I is false but Statement II is true

Solution

1,2,3-Trihydroxypropane is glycerol. Glycerol decomposes near its normal boiling point, so simple atmospheric distillation is not used. It is purified by distillation under reduced pressure (or steam distillation). Statement I is therefore false.

Azeotropes boil at a constant composition that matches their vapour composition; fractional distillation cannot separate them. Statement II is true.

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