NEET2023Chemistry
Q.
Consider the following reaction and identify the product (P).

- A
1
- B
2
- C
3
- D
4
Solution

With HBr, the alcohol is protonated and loses water to form a secondary carbocation at C2. A 1,2-hydride shift from the adjacent C3 (which bears the methyl branch) converts this into a more stable tertiary carbocation at C3.
Bromide then attacks the tertiary cation to give 2-bromo-2-methylbutane.
tertiary product is favoured.
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